The Cottrell Experiment and Diffusion Limitation 3/3

In this chapter the electrochemical double layer and its features are discussed. The electrochemical double layer acts as a capacitor and every change in the potential of the electrode will induce a capacitive charging current that is caused by physics not by a chemical reaction. This current decays exponentially. 

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PDF) Comparison between Cottrell diffusion and moving boundary models for determination of the chemical diffusion coefficients in ion-insertion electrodes