Enabling 4.6 V LiNi0.6Co0.2Mn0.2O2 cathodes with excellent structural stability: combining surface LiLaO2 self-assembly and subsurface La-pillar engineering
The solution proposed in this article is expected to provide direction for managing the internal structure and interface stability of NCM and can be extended to other cathode applications.
a) Schematic illustration of the synthesis process of as prepared
XRD patterns of NCM-811, NCML-811, and NCMLF-811 at 10–70
Discharge/charge curves of the first three and the 100th cycles of the
image.oaes.cc/3d935bff-486e-4a99-acb1-20f76948b38c
Equivalent Resistance Values of La 3+ −Al 3+ Co- doped NCM811
a) Initial charge–discharge voltage profiles of U‐LNCM, P‐LNCM, and
A) Ionic and (B) electronic conductivity of NCM622, NCM622-La and
Atomic‐resolution STEM images of a) P‐LNCM pristine, b) P‐LNCM
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Lithium metal stabilization for next-generation lithium-based batteries: from fundamental chemistry to advanced characterization and